Skip to main content

Blog entry by Finlay Christian

labo-productoftheyear-2024-award-2.jpg

Measuring non-spherical particles presents a unique set of challenges that go beyond the scope of traditional particle analysis methods designed for idealized spherical shapes. In industries ranging from ceramics, the particles involved are rarely perfect spheres. Their irregular geometries—aggregated—introduce significant complexity when attempting to determine size and geometry, distribution, and surface properties accurately. Overcoming these challenges requires a combination of cutting-edge equipment, statistical modeling, and a expert insight of the dynamic response of these particles under different environmental setups.

One of the primary difficulties lies in defining what constitutes the "extent" of a non-spherical particle. For spheres, diameter is a straightforward parameter, but for irregular shapes, multiple dimensions must be considered. A single value such as sphere-equivalent size can be misleading because it fails to capture the true morphology. To address this, modern systems now employ multi-dimensional descriptors such as elongation factor, roundness, linear deviation, and outline completeness. These parameters provide a more complete picture of particle shape and are essential for correlating functional attributes like flowability, void fraction, and catalytic efficiency with particle geometry.

Another major challenge is the limitation of traditional techniques such as laser diffraction, which assume spherical particles to calculate size distributions. When applied to non-spherical particles, these methods often produce systematic errors because the light intensity profiles are interpreted based on idealized assumptions. To mitigate this, researchers are turning to digital imaging platforms that capture sharp planar or three-dimensional representations of individual particles. Techniques like real-time particle visualization and micro-CT scanning allow non-destructive imaging and measurement of shape features, providing validated results for complex morphologies.

Sample preparation also plays a critical role in obtaining accurate measurements. Non-spherical particles are more prone to orientation effects during measurement, especially in liquid suspensions or powder beds. flocking, sedimentation, and shear-dependent reorientation can distort the observed shape distribution. Therefore, careful dispersion protocols, including the use of appropriate surfactants, sonication, and regulated shear, are necessary to ensure that particles are measured in their original morphology. In dry powder measurements, electrostatic charges and adhesion require the use of air-jet dispersers to break up aggregates without inducing structural damage.

Data interpretation adds another layer of complexity. With thousands to millions of individual particles being analyzed, the resulting dataset can be high-dimensional. Machine learning algorithms are increasingly being used to categorize morphologies, reducing subjectivity and increasing throughput. pattern recognition algorithms can group particles by shape proximity, helping to identify distinct fractions that might be missed by standard methods. These algorithms can be trained on certified standards, allowing for standardized outcomes across different laboratories.

Integration of multiple measurement techniques is often the most effective approach. Combining digital morphometry with light scattering or chemical mapping enables complementary verification and provides a more holistic understanding of both size and chemical composition. Calibration against certified reference materials, such as validated synthetic morphologies, further enhances measurement accuracy.

Ultimately, overcoming the challenges of non-spherical particle measurement requires moving beyond reductive models and embracing comprehensive morphometric profiling. It demands integration of equipment engineers, data scientists, and domain specialists to tailor 動的画像解析 solutions for each specific use case. As industries increasingly rely on particle morphology to control product performance—from drug dissolution rates to printability and layer adhesion—investing in next-generation characterization tools is no longer optional but essential. The future of particle characterization lies in its ability to capture not just its size metric, but what it truly looks like.